Sublimation ink transfers are a great way to go when working with polyester fabrics. Since you are transferring ink only and not transferring polymer film with a heat transfer paper, you will retain more of the moisture-wicking properties that polyesters fabrics are known for.
However, Neenah makes very good products and they try to be cross-compatible between different fabrics. You will be able to use the Neenah 3G Jet Opaque with polyester fabrics. If you are working with light color shirts, give the Neenah Jet Pro Soft Stretch for Active Wear a shot, this heat transfer paper is made specifically for synthetic fabrics.