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Should be as simple as placing the t-shirt on the press, placing the cut vinyl on the t-shirt, placing a teflon sheet (said whiteish material, this is very important - without it, the transfer will glue itself to the top of the heat press) over the vinyl transfer, and pressing the shirt.
I haven't personally done vinyl transfers though, and you might consider asking over at http://groups.yahoo.com/group/Heat_Transfers_For_Desktop_Printers/ for more information.
I haven't personally done vinyl transfers though, and you might consider asking over at http://groups.yahoo.com/group/Heat_Transfers_For_Desktop_Printers/ for more information.