Yes you can, very easily. You want to print a discharge underbase first similar to how you would print a plastisol under base, or you can pigment your discharge ink itself, but the second option usually requires an ink matching system if you are trying to get specific pantones.
If you do a search for 'discharge underbase' on this site you will get a lot of helpful info...
If you do a search for 'discharge underbase' on this site you will get a lot of helpful info...