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Could be a couple of things.

1) pretreatment and/or ink not fully cured (think screen printing and what happens when plastisol is not cured)

2) bad mixture of pretreatment

3) Not enough pretreatment or too much. There is a window of acceptable pretreatment.
 

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Make sure you cure the pre-treat under high pressure. If you are curing the final print on a heatpress then it needs light pressure, if you are curing by just resting the heatpress on the shirt like you can on a GT541 then your design will flake off (been there and done that:eek:)
 
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