a tshirt at some point, worn by someone, is brought up in discussion and if THAT person who hears where they got the shirt from looks up your site
This happens more times than I can count (based on customer responses of how they found my site).
Depending on the t-shirt I'm wearing, I also seem to get a lot of comments like "where did you get that t-shirt" (although most people offline get glazed over eyes when I say "threadless" or "t26.com"

) I'm actually a bit surprised by this phenomenon, since I wouldn't consider myself an overly "approachable" person in "real life"

T-Shirts can definitely be interesting conversation starters.