In Photoshop go to window/show brushes/ in the brushes pallet window go to the right top and open the options. Hit expanded view and you should have a whole bunch of brush styles you can choose from.. That is the basic.. Adobe has an exchange where there are tons of free brushes and styles and effects
Oh yeah.. If you dont utilize Adobe Bridge, you should open that program ( comes with CS3 ) Once that is up and running u should see a link for Bridge Home.. click it.. It will take you to tons of links and topics and tools and videos
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